It is called a hairspray for a reason as its sticky substance is meant to keep hair in place and not your makeup. Instead, you can opt for an actual makeup spray or use some translucent blotting powder using a hairspray leave your skin dry, flaky and not at all fresh.

Deodorants have properties that suppress sweat and it is meant for that and not for your skin. It is an antiperspirant. Use of the powder will leave your skin red, blotchy and irritated, and it also might even lead to a breakout. So do avoid using the deo sticks as a matte primer.